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Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, I)

Abstract
Postsynthetic chemical transformations of colloidal nanocrystals, such as ion-exchange reactions, provide an avenue to compositional fine-tuning or to otherwise inaccessible materials and morphologies. While cation-exchange is facile and commonplace, anion-exchange reactions have not received substantial deployment. Here we report fast, low-temperature, deliberately partial, or complete anion-exch...
Keywords
Halide
Nanocrystal
Photoluminescence
Caesium
Ion exchange
Luminescence
Ion
Inorganic chemistry
Colloid
Quantum dot
Materials science
Chemistry
Nanotechnology
Physical chemistry
Optoelectronics
Organic chemistry


pdf file

Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, I)
pdf file

Fast Anion-Exchange in Highly Luminescent Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, I)

Abstract
Postsynthetic chemical transformations of colloidal nanocrystals, such as ion-exchange reactions, provide an avenue to compositional fine-tuning or to otherwise inaccessible materials and morphologies. While cation-exchange is facile and commonplace, anion-exchange reactions have not received substantial deployment. Here we report fast, low-temperature, deliberately partial, or complete anion-exch...
Keywords
Halide
Nanocrystal
Photoluminescence
Caesium
Ion exchange
Luminescence
Ion
Inorganic chemistry
Colloid
Quantum dot
Materials science
Chemistry
Nanotechnology
Physical chemistry
Optoelectronics
Organic chemistry


pdf file