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Chemical Decomposition of Iron in Spanish Coal Pyrolysis Identified by Mossbauer Spectroscopy at Different Temperatures

Abstract
Three chars from lignite (Se) sub bituminous (AA6), bituminous (BCA) Spanish coals produced at 673 K, 773K and 873K were analyzed by Mossbauer spectroscopy at room temperature, and 80K, except BCA char produced at 873K, its analysis was extended down to 10K.Least square fit analysis for the spectra of Se chars showed that, jarosite/Fe 3+ was hydrolysed into rozenite/Fe 2+ at 873K.Pyrite was reduce...
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Keywords
Mössbauer spectroscopy
Decomposition
Pyrolysis
Coal
Spectroscopy
Materials science
Chemistry
Thermal decomposition
Crystallography
Organic chemistry
Physics
Quantum mechanics


pdf file

Chemical Decomposition of Iron in Spanish Coal Pyrolysis Identified by Mossbauer Spectroscopy at Different Temperatures
pdf file

Chemical Decomposition of Iron in Spanish Coal Pyrolysis Identified by Mossbauer Spectroscopy at Different Temperatures

Abstract
Three chars from lignite (Se) sub bituminous (AA6), bituminous (BCA) Spanish coals produced at 673 K, 773K and 873K were analyzed by Mossbauer spectroscopy at room temperature, and 80K, except BCA char produced at 873K, its analysis was extended down to 10K.Least square fit analysis for the spectra of Se chars showed that, jarosite/Fe 3+ was hydrolysed into rozenite/Fe 2+ at 873K.Pyrite was reduce...
View PDF
Keywords
Mössbauer spectroscopy
Decomposition
Pyrolysis
Coal
Spectroscopy
Materials science
Chemistry
Thermal decomposition
Crystallography
Organic chemistry
Physics
Quantum mechanics


pdf file