A series of four binuclear complexes [Cr2(CO)2L2] (1), [Mo2O4(L)2] (2), and [W2O4(L)2] (3) [Mo2O5(CO)L].H2O (4) were synthesized from the reaction of [M(CO)6] (M = Cr, Mo and W) with 6,6'-(([1,1'-biphenyl]-4,4' diylbis(azaneylylidene)) bis(methaneylylidene)) bis(2,4-dichlorophenol) H2L in THF.The structures of the ligand and its complexes were characterized using elemental studies, IR, mass, UV-vi...
A series of four binuclear complexes [Cr2(CO)2L2] (1), [Mo2O4(L)2] (2), and [W2O4(L)2] (3) [Mo2O5(CO)L].H2O (4) were synthesized from the reaction of [M(CO)6] (M = Cr, Mo and W) with 6,6'-(([1,1'-biphenyl]-4,4' diylbis(azaneylylidene)) bis(methaneylylidene)) bis(2,4-dichlorophenol) H2L in THF.The structures of the ligand and its complexes were characterized using elemental studies, IR, mass, UV-vi...